Acidity and nucleophilic reactivity of glutathione persulfide

Persulfides (RSSH/RSS2) participate in sulfur trafficking and metabolic processes, and are proposed to mediate the signaling effects of hydrogen sulfide (H2S). Despite their growing relevance, their chemical properties are poorly understood. Herein, we studied experimentally and computationally the...

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Dettagli Bibliografici

Autore principale:	Benchoam, Dayana (author)
Altri autori:	Semelak, Jonathan A. (author), Cuevasanta, Ernesto (author), Mastrogiovanni, Mauricio (author), Grassano, Juan S. (author), Ferrer-Sueta, Gerardo (author), Zeida, Ari (author), Trujillo, Madia (author), Möller, Matías N. (author), Estrin, Darío A (author), Álvarez, Beatriz (author)
Natura:	article
Lingua:	inglese
Pubblicazione:	2020
Soggetti:	Enzyme mechanism Glutathione Hydrogen sulfide Persulfide Sulfhydryl Sulfur Thiol pKa α effect
Accesso online:	https://hdl.handle.net/20.500.12008/26646
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