World‑class amethyst‑agate geodes from Los Catalanes, Northern Uruguay: genetic implications from fluid inclusions and stable isotopes

Información suplemetaria en: doi.org/10.1007/s00126-024-01310-2

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Autor Principal: Arduin Rode, Fiorella (author)
Outros autores: Sosa, Graciela (author), Van den Kerkhof, Alfons (author), Krüger, Yves (author), Bajnai, David (author), Pack, Andreas (author), Di Rocco, Tommaso (author), Oyhantçabal Cironi, Pedro Bernardo (author), Wemmer, K. (author), Herwartz, Daniel (author), Klipsch, Swea (author), Wiegand, Bettina (author), Siegesmund, S. (author), Hueck, M. (author)
Formato: article
Idioma:inglés
Publicado: 2025
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Acceso en liña:https://hdl.handle.net/20.500.12008/51035
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author Arduin Rode, Fiorella
author2 Sosa, Graciela
Van den Kerkhof, Alfons
Krüger, Yves
Bajnai, David
Pack, Andreas
Di Rocco, Tommaso
Oyhantçabal Cironi, Pedro Bernardo
Wemmer, K.
Herwartz, Daniel
Klipsch, Swea
Wiegand, Bettina
Siegesmund, S.
Hueck, M.
author2_role author
author
author
author
author
author
author
author
author
author
author
author
author
author_browse Arduin Rode, Fiorella
Bajnai, David
Di Rocco, Tommaso
Herwartz, Daniel
Hueck, M.
Klipsch, Swea
Krüger, Yves
Oyhantçabal Cironi, Pedro Bernardo
Pack, Andreas
Siegesmund, S.
Sosa, Graciela
Van den Kerkhof, Alfons
Wemmer, K.
Wiegand, Bettina
author_facet Arduin Rode, Fiorella
Sosa, Graciela
Van den Kerkhof, Alfons
Krüger, Yves
Bajnai, David
Pack, Andreas
Di Rocco, Tommaso
Oyhantçabal Cironi, Pedro Bernardo
Wemmer, K.
Herwartz, Daniel
Klipsch, Swea
Wiegand, Bettina
Siegesmund, S.
Hueck, M.
author_role author
collection COLIBRI
dc.contributor.none.fl_str_mv Arduin Rode Fiorella
Sosa Graciela
Van den Kerkhof Alfons
Krüger Yves
Bajnai David
Pack Andreas
Di Rocco Tommaso
Oyhantçabal Cironi Pedro Bernardo, Universidad de la República (Uruguay). Facultad de Ciencias. Instituto de Ciencias Geológicas.
Wemmer K.
Herwartz Daniel
Klipsch Swea
Wiegand Bettina
Siegesmund S.
Hueck M.
dc.creator.none.fl_str_mv Arduin Rode, Fiorella
Sosa, Graciela
Van den Kerkhof, Alfons
Krüger, Yves
Bajnai, David
Pack, Andreas
Di Rocco, Tommaso
Oyhantçabal Cironi, Pedro Bernardo
Wemmer, K.
Herwartz, Daniel
Klipsch, Swea
Wiegand, Bettina
Siegesmund, S.
Hueck, M.
dc.date.none.fl_str_mv 2025-08-13T17:24:37Z
2025-08-13T17:24:37Z
2025
dc.format.none.fl_str_mv 25 h
application/pdf
dc.identifier.none.fl_str_mv Arduin Rode, F, Sosa, G, Van den Kerkhof, A [y otros autores]. "World‑class amethyst‑agate geodes from Los Catalanes, Northern Uruguay: genetic implications from fluid inclusions and stable isotopes". Mineralium Deposita. [en línea] 2025, 60(4): 697-721. 25 h. DOI: 10.1007/s00126-024-01310-2
1432-1866
https://hdl.handle.net/20.500.12008/51035
10.1007/s00126-024-01310-2
dc.language.none.fl_str_mv en
eng
dc.publisher.none.fl_str_mv Springer
dc.relation.none.fl_str_mv Mineralium Deposita, 2025, 60(4): 697-721.
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
Licencia Creative Commons Atribución (CC - By 4.0)
dc.source.none.fl_str_mv reponame:COLIBRI
instname:Universidad de la República
instacron:Universidad de la República
dc.subject.none.fl_str_mv Amethyst geodes
Fluid inclusions
Isotope geochemistry
Triple oxygen isotopes
Los Catalanes Gemmological District
Paraná-Etendeka LIP
dc.title.none.fl_str_mv World‑class amethyst‑agate geodes from Los Catalanes, Northern Uruguay: genetic implications from fluid inclusions and stable isotopes
dc.type.none.fl_str_mv Artículo
info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
description Información suplemetaria en: doi.org/10.1007/s00126-024-01310-2
eu_rights_str_mv openAccess
format article
id anni_9741cc52414f3d299eb73cd8024cc3d4
identifier_str_mv Arduin Rode, F, Sosa, G, Van den Kerkhof, A [y otros autores]. "World‑class amethyst‑agate geodes from Los Catalanes, Northern Uruguay: genetic implications from fluid inclusions and stable isotopes". Mineralium Deposita. [en línea] 2025, 60(4): 697-721. 25 h. DOI: 10.1007/s00126-024-01310-2
1432-1866
10.1007/s00126-024-01310-2
instacron_str Universidad de la República
institution Universidad de la República
instname_str Universidad de la República
language eng
language_invalid_str_mv en
network_acronym_str anni
network_name_str oai-lr-anni
oai_identifier_str oai:colibri.udelar.edu.uy:20.500.12008/51035
publishDate 2025
publishDateSort 2025
publisher.none.fl_str_mv Springer
reponame_str COLIBRI
repository.mail.fl_str_mv
repository.name.fl_str_mv
repository_id_str
rights_invalid_str_mv Licencia Creative Commons Atribución (CC - By 4.0)
spelling World‑class amethyst‑agate geodes from Los Catalanes, Northern Uruguay: genetic implications from fluid inclusions and stable isotopesArduin Rode, FiorellaSosa, GracielaVan den Kerkhof, AlfonsKrüger, YvesBajnai, DavidPack, AndreasDi Rocco, TommasoOyhantçabal Cironi, Pedro BernardoWemmer, K.Herwartz, DanielKlipsch, SweaWiegand, BettinaSiegesmund, S.Hueck, M.Amethyst geodesFluid inclusionsIsotope geochemistryTriple oxygen isotopesLos Catalanes Gemmological DistrictParaná-Etendeka LIPInformación suplemetaria en: doi.org/10.1007/s00126-024-01310-2The amethyst and agate geodes from the Los Catalanes Gemmological District in Uruguay represent one of the main deposits of its kind worldwide. The geometry of the deposit is horizontal, with an irregular distribution of amethyst geodes within the upper level of the basalt lava flows and shows strong variations in their abundance, as well as quality, geometry, and shape. Reliable exploration guides are scarce, and the limited knowledge of the geological parameters controlling its occurrence makes exploration unpredictable, leading to inaccurate reserve estimation. Based on cutting-edge methods including nucleation-assisted microthermometry of one-phase fluid inclusions and determination of triple oxygen isotope in silicates and carbonates, as well as analysis of geode-hosted water and groundwater, we estimate the crystallisation temperatures in the range between 15 and 60 °C. These low temperatures point to amethyst crystallisation after the emplacement of the complete basalt pile. The mineralising fluid shows isotopic signatures consistent with meteoric water and very low salinities from pure water up to rarely over 3 wt% NaCl-eq., likely sourced from the groundwater hosted in the aquifers in the basaltic sequence and underlying units. Based on the insights provided by the new data, we propose the combination of open- and closed-system crystallisation inside pre-existing cavities due to the episodic infiltration of meteoric water in a rather stable geological context.SpringerArduin Rode FiorellaSosa GracielaVan den Kerkhof AlfonsKrüger YvesBajnai DavidPack AndreasDi Rocco TommasoOyhantçabal Cironi Pedro Bernardo, Universidad de la República (Uruguay). Facultad de Ciencias. Instituto de Ciencias Geológicas.Wemmer K.Herwartz DanielKlipsch SweaWiegand BettinaSiegesmund S.Hueck M.2025-08-13T17:24:37Z2025-08-13T17:24:37Z2025Artículoinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion25 happlication/pdfArduin Rode, F, Sosa, G, Van den Kerkhof, A [y otros autores]. "World‑class amethyst‑agate geodes from Los Catalanes, Northern Uruguay: genetic implications from fluid inclusions and stable isotopes". Mineralium Deposita. [en línea] 2025, 60(4): 697-721. 25 h. DOI: 10.1007/s00126-024-01310-21432-1866https://hdl.handle.net/20.500.12008/5103510.1007/s00126-024-01310-2reponame:COLIBRIinstname:Universidad de la Repúblicainstacron:Universidad de la RepúblicaenengMineralium Deposita, 2025, 60(4): 697-721.Las obras depositadas en el Repositorio se rigen por la Ordenanza de los Derechos de la Propiedad Intelectual de la Universidad de la República.(Res. Nº 91 de C.D.C. de 8/III/1994 – D.O. 7/IV/1994) y por la Ordenanza del Repositorio Abierto de la Universidad de la República (Res. Nº 16 de C.D.C. de 07/10/2014)info:eu-repo/semantics/openAccessLicencia Creative Commons Atribución (CC - By 4.0)oai:colibri.udelar.edu.uy:20.500.12008/510352026-04-14T10:10:55Z
spellingShingle World‑class amethyst‑agate geodes from Los Catalanes, Northern Uruguay: genetic implications from fluid inclusions and stable isotopes
Arduin Rode, Fiorella
Amethyst geodes
Fluid inclusions
Isotope geochemistry
Triple oxygen isotopes
Los Catalanes Gemmological District
Paraná-Etendeka LIP
status_str publishedVersion
title World‑class amethyst‑agate geodes from Los Catalanes, Northern Uruguay: genetic implications from fluid inclusions and stable isotopes
title_full World‑class amethyst‑agate geodes from Los Catalanes, Northern Uruguay: genetic implications from fluid inclusions and stable isotopes
title_fullStr World‑class amethyst‑agate geodes from Los Catalanes, Northern Uruguay: genetic implications from fluid inclusions and stable isotopes
title_full_unstemmed World‑class amethyst‑agate geodes from Los Catalanes, Northern Uruguay: genetic implications from fluid inclusions and stable isotopes
title_short World‑class amethyst‑agate geodes from Los Catalanes, Northern Uruguay: genetic implications from fluid inclusions and stable isotopes
title_sort World‑class amethyst‑agate geodes from Los Catalanes, Northern Uruguay: genetic implications from fluid inclusions and stable isotopes
topic Amethyst geodes
Fluid inclusions
Isotope geochemistry
Triple oxygen isotopes
Los Catalanes Gemmological District
Paraná-Etendeka LIP
url https://hdl.handle.net/20.500.12008/51035